Wow! I've been following your stuff for a while now and I can honestly say this is your best to date. I especially love the the sharpness of his face and the lighting on his shoulders.
Some minute criticism though
-Immediately above each shoulder it is very easy to tell where you smudged from. If all your layers are still separate, I would return to that and either blend/smudge it more, or perhaps remove it all together. I think it may look better if you kept with the green "shards" as your background, not some ambiguous brownish blurs.
-Lighting is a hard thing to master, I understand, (well, I don't actually...I never "mastered" it myself lol) but you have 2 sources of light in the sig which throws off the balance. Immediately behind the render (looks best) and the far left bottom corner.
If you can adjust these 2 things it will become one righteous hunk o' photoshop gold.





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